Chiral organophosphorous compounds are very important in catalysis, organic syntheses, and medicinal chemistry. However, catalytic enantioselective protocols for the axially chiral allenyl phosphorous compounds have never been reported. Herein, a palladium-catalyzed enantioselective carbon-phosphorous bond formation reaction affording axially chiral allenyl phosphonates has been developed. The reaction enjoys high yields and ee accommodating a wide range of functional groups. Mechanistic studies have unveiled an overwhelming kinetic resolution process. Link!